Skip to main content

Table 1 Pseudo-first-order and second-order rate constants for the reaction of [MoIVO2(paoH)22−] = 1.5 × 10−3 mol dm−3, D = 77.9, λmax = 560 nm, and T = 300 K

From: The study of Piszkiewicz’s and Berezin’s models on the redox reaction of allylthiourea and bis-(2-pyridinealdoximato)dioxomolybdate(IV) complex in an aqueous acidic medium

102[ATH] mol dm−3

μ mol dm−3

[H +] mol dm−3

104kob s−1

102k2 dm3 mol−1 s−1

1.50

0.10

0.01

5.00

3.07

3.00

0.10

0.01

9.10

3.03

4.50

0.10

0.01

13.82

3.07

6.00

0.10

0.01

16.39

3.07

7.50

0.10

0.01

18.94

3.05

9.00

0.10

0.01

23.29

3.06

10.5

0.10

0.01

27.00

3.05

12.0

0.10

0.01

30.46

3.05

13.5

0.10

0.01

33.84

3.05

15.0

0.10

0.01

37.27

3.04

4.50

0.10

0.01

13.82

3.07

4.50

0.10

0.15

09.36

2.08

4.50

0.10

0.20

07.47

1.66

4.50

0.10

0.25

06.84

1.52

4.50

0.10

0.30

06.62

1.47

4.50

0.10

0.35

05.94

1.32

4.50

0.10

0.40

04.68

1.04

4.50

0.10

0.45

04.11

0.91

4.50

0.10

0.50

03.74

0.83

4.50

0.10

0.55

02.30

0.51

4.50

0.10

0.20

07.47

1.66

4.50

0.10

0.01

13.82

3.07

4.50

0.20

0.01

14.05

3.12

4.50

0.30

0.01

13.82

3.07

4.50

0.40

0.01

13.82

3.07

4.50

0.50

0.01

13.82

3.07

4.50

0.60

0.01

13.82

3.07

4.50

0.70

0.01

13.82

3.07

4.50

0.80

0.01

13.82

3.07

4.50

0.90

0.01

14.05

3.07