Table 3 Effect of counter-ions on the rate constants for the reaction of [MoIVO2(paoH)2]2− and ATH at [MoIVO2(paoH)22−] = 1.5 × 10−3 mol dm−3, [ATH] = 4.50 × 10−2 mol dm−3, and µ = 0.1 mol dm−3
Ion | 103[Ion], mol dm3 | 104kob, s−1 | 102k2, dm3 mol−1 s−1 | Ion | 103[Ion], mol dm3 | 104kob, s−1 | 102k2, dm3 mol−1 s−1 |
|---|---|---|---|---|---|---|---|
Ca2+ | 0.00 | 10.13 | 3.81 | HCOO− | 0.00 | 13.82 | 13.82 |
8.00 | 11.05 | 7.16 | 8.00 | 13.82 | 3.07 | ||
12.0 | 12.67 | 8.19 | 12.0 | 13.36 | 2.96 | ||
16.0 | 13.82 | 9.72 | 16.0 | 13.82 | 3.07 | ||
20.0 | 14.51 | 10.74 | 20.0 | 13.59 | 3.07 | ||
24.0 | 17.04 | 12.79 | 24.0 | 13.36 | 2.96 | ||
28.0 | 18.19 | 13.82 | 28.0 | 13.82 | 3.07 | ||
32.0 | 20.49 | 16.89 | 32.0 | 13.82 | 3.07 |